At ItalianSide, we have a big collection of old photos from almost every town in Toscana and in Italy (We have more than 90% of Italian towns in our pictures archives!).
We have several images of Montepulciano too and here you can see one of them (click on the picture to enlarge).

If you are interested in historical maps, here you can see an old map (1800) of Montepulciano and its area.

If you are interested in this or other pictures with no watermark of Montepulciano just send an email to montepulciano@italianside.com, with your request.